Tris(diisopropyl dithiophosphato-κ2 S,S′)ruthenium(III)
نویسندگان
چکیده
In the title complex, [Ru(C6H14O2PS2)3], the coordination environment of the Ru(III) atom is distorted octa-hedral, defined by six S atoms from three S,S'-bidentate diisopropyl di-thio-phosphate ligands. The average Ru-S bond length is 2.41 (1) Å and the average S-Ru-S bite angle is 81.13 (19)°.
منابع مشابه
Synthesis and Characterization of Ruthenium Amidinate Complexes as Precursors for Vapor Deposition
Three new ruthenium amidinate complexes were prepared: tris(diisopropylacetamidinato)-ruthenium(III), Ru(iPrNC(Me)NiPr)3 4; bis(diisopropyl-acetamidinato)ruthenium(II) dicarbonyl, Ru( iPrNC(Me)NiPr)2(CO)2 5; and bis(ditert-butylacetamidinato)ruthenium(II) dicarbonyl, Ru(tBuNC(Me)NtBu)2(CO)2 6. They have been synthesized and characterized by H NMR, TG and X-ray structure analysis. These three co...
متن کاملChemiluminescence from the reaction of tin(II) with tris(2,2'-bipyridyl)ruthenium(III).
Unlike many other metal and metalloid ions, tin(II) elicits intense, analytically useful chemiluminescence upon reaction with tris(2,2'-bipyridyl)ruthenium(III) in acidic aqueous solution. This finding provides new insight into the nature of this widely used reagent and has enabled the first direct, selective determination of a metal ion with tris(2,2'-bipyridyl)ruthenium(III).
متن کاملPoly[μ3-chlorido-μ2-chloridodichlorido(μ-dimethyl sulfoxide-κ2 O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ2 N:N′)ruthenium(III)sodium]
The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa-hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](-) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom. The average of the four Ru-Cl bond lengths is 2.355 (15) Å, and the Ru-S and Ru-N bond lengths are 2.2853 (3) and 2.1165 (...
متن کاملTris(N-benzyl-N-methyldithiocarbamato-κ2 S,S′)(1,10-phenanthroline-κ2 N,N′)europium(III)
In the title compound, [Eu(C(9)H(10)NS(2))(3)(C(12)H(8)N(2))], the Eu(III) atom exists in a distorted square-anti-prismatic coordination geometry. Both dithio-carbamate and the N-heterocyclic ligands function in a chelating mode.
متن کاملTris[N-(2-furoyl)-N,N′-diphenylthioureato-κ2 O,S]cobalt(III)
In the title compound, [Co(C(18)H(13)N(2)O(2)S)(3)], the Co(III) atom is coordinated by the S and O atoms of three N-furoyl-N',N'-diphenyl-thio-urea ligands in a slightly distorted octa-hedral geometry. The three O atoms are arranged fac, as are the three S atoms.
متن کامل